Please use the following code.
Sub Req_AfterPost
On Error Resume Next
Dim strTo
Dim strSubject
Dim strComment
Set tdc = TDConnection
Set objReqFactory = tdc.reqFactory
Set ReqFilter = objReqFactory.Filter
pQCAdmin = ''singu.sivanaga@orasi.com'' 'Send the email to the Quality Center Administrator
'Change for your own environment
Req_AssignedTo = Req_Fields.Field(''RQ_USER_01'').Value
pEmail = tdc.Customization.Users.User(Req_AssignedTo).Email
If len(pEmail)<1 Then 'If Requirement Author's email address is blank
pEmail = pQCAdmin 'Send the email to the Quality Center Administrator
Req_AssignedTo = pEmail 'Change for your own environment
End If
If Req_Fields(''RQ_REQ_REVIEWED'').Value = ''ReadyforReview'' Then
strTO = Req_AssignedTo
strSubject = ''The Status for Requirement # '' & Req_Fields(''RQ_REQ_ID'').value & '' Has Changed to '' & Req_Fields(''RQ_REQ_REVIEWED'').value
strComment = ''The Status for Requirement # '' & Req_Fields(''RQ_REQ_ID'').value & '' Has Changed to '' & Req_Fields(''RQ_REQ_REVIEWED'').value
TDConnection.sendmail strTo, strFrom, strSubject, strComment, NULL, ''HTML''
Set TDConnection = nothing
MsgBox ''Mail Sent''
End if
Set tdc = nothing
Set objReqFactory = nothing
On Error GoTo 0
End Sub